Aluminium Nitrate

Aluminium Nitrate

Origin
: China
CAS Number
: 7784-27-2
HS Code
: 2834.29.90
Basic Info
IUPAC Name
: aluminium trinitrate nonahydrate
Molecular Formula
: Al(NO3)3·9H2O
Molecular Weight (g/mol)
: 375.1300
Synonyms & Trade Names
: Aluminium nitrate; Aluminum nitrate; Al(NO3)3.9H2O
Purity / Assay (%)
: 98% min
Grade / Quality Level
: Technical Grade
Physical Form
: Solid
Concentration
: Pure substance
Appearance / Color
: White to off-white solid
Odor
: Odorless
Melting Point (°C)
: 73.0000
Density (g/cm³)
: 1.7200
Solubility in Water
: Freely soluble
Signal Word
: Warning
UN Number
: 1438
GHS Hazard Class
: Oxidizer; Skin irritant; Eye irritant
H-Statements
: H272|H315|H319
P-Statements
: P210|P220|P221|P260|P264|P280
REACH Status
: Registered
Drug Precursor Status
: Non-precursor
Storage Class (GHS)
: 5.1
Storage Conditions
: Cool, dry; oxidizer; away from combustibles
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Technical Document

About Aluminium Nitrate

Aluminium nitrate most commonly exists in its hydrated crystal form, aluminium nitrate nonahydrate, Al(NO3)3·9H2O. It is a white crystalline, water-soluble salt with a molecular weight of 375.15 g/mol. It melts at 73oC and decomposes at 150oC. It is an odourless material and will react explosively upon contact with organic compounds. Its solution is acidic and is a strong oxidising reagent. It can easily dissolve in water and ethanol but not in acetic acid and ethyl acetate.

Manufacturing Process:
Contrary to aluminium chloride, it cannot be synthesised just by adding nitrates containing compounds (such as nitric acid) to aluminium metal. This is because aluminium will form a passivation layer, where there will be a creation of an outer layer on the metal to prevent further chemical reactions from occurring. Hence, aluminium nitrate is typically prepared by the addition of nitric acid to aluminium chloride. Nitrosyl chloride is generated as a byproduct which oozes out of the solution as a gas.

Aluminium nitrate can also be produced by mixing solution of lead nitrate with aluminium sulfate via a metathesis reaction. Insoluble lead sulfate precipitates out of the solution, giving a solution with aluminium nitrate.