Dioctyl Adipate (DOA)

Dioctyl Adipate (DOA)

Origin
: China, Taiwan
CAS Number
: 123-79-5
HS Code
: 291712
Basic Info
IUPAC Name
: dioctyl hexanedioate
Molecular Formula
: C22H42O4
Molecular Weight (g/mol)
: 370.5700
Synonyms & Trade Names
: Dioctyl adipate; DOA; Di-2-ethylhexyl adipate; Bis(2-ethylhexyl) adipate
Purity / Assay (%)
: 99% min
Grade / Quality Level
: Technical Grade
Physical Form
: Liquid
Concentration
: Pure substance
Appearance / Color
: Clear to slightly colored liquid
Odor
: Almost odorless
Melting Point (°C)
: -70.0000
Boiling Point (°C)
: 215 (at 5mmHg)
Density (g/cm³)
: 0.9280
Solubility in Water
: Insoluble in water
UN Number
: Not applicable
H-Statements
: None
P-Statements
: P260
REACH Status
: Registered
Drug Precursor Status
: Non-precursor
Storage Class (GHS)
: 10
Storage Conditions
: Cool, dry place
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Technical Document

Brief Overview
Dioctyl adipate (DOA) is a clear, colorless, and odorless liquid organic compound that belongs to the family of adipate esters. It is derived from the reaction of adipic acid with 2-ethylhexanol and is commonly used as a plasticizer in various industrial applications. DOA is known for its low volatility, good electrical properties, and excellent low-temperature flexibility, which makes it a popular choice for applications that require flexibility even at low temperatures. It is also widely used in the food packaging industry, as it is approved by the FDA for use as a food contact material. However, DOA is not without its drawbacks. It has a relatively low resistance to extraction by water, which can limit its use in certain applications. Additionally, it has a limited resistance to high-temperature environments, which can cause it to degrade over time. Despite these limitations, DOA remains a widely used and important industrial chemical.
Manufacturing Process
Esterification: Adipic acid and 2-ethylhexanol are mixed together in the presence of a catalyst such as sulfuric acid. The mixture is heated to around 220-240°C while being stirred continuously. The reaction produces a mixture of esters, including DOA, along with water as a byproduct.

Purification: The mixture is then allowed to cool, and the DOA is separated from the other esters using a distillation column. The DOA is collected as a clear, colorless liquid.

Refining: The DOA is further purified using various refining techniques, such as filtration or centrifugation, to remove any impurities that may be present.