Sodium Formate

Sodium Formate

CAS Number
: 141-53-7
HS Code
: 2915.12.00
Basic Info
IUPAC Name
: sodium formate
Molecular Formula
: CHNaO2
Molecular Weight (g/mol)
: 68.0100
Synonyms & Trade Names
: Sodium formate; Formic acid sodium salt; Mravencian sodny
Purity / Assay (%)
: 99.5% min
Grade / Quality Level
: Technical Grade
Physical Form
: Solid
Concentration
: Pure substance
Appearance / Color
: White to off-white solid
Odor
: Odorless
Melting Point (°C)
: 253.0000
Density (g/cm³)
: 1.9200
Solubility in Water
: Freely soluble
UN Number
: Not applicable
H-Statements
: None
P-Statements
: P260
REACH Status
: Registered
Drug Precursor Status
: Non-precursor
Storage Class (GHS)
: 13
Storage Conditions
: Cool, dry place; keep sealed
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Technical Document
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Brief Overview
Sodium formate HCOONa, also known as sodium methanoate, is the sodium salt of formic acid. It is a white, water-soluble crystalline powder with hygroscopic properties. Sodium formate is widely used in various industries, including leather tanning, oil drilling, de-icing, and as a reducing agent in chemical processes. In the leather industry, it is commonly used to reduce hexavalent chromium (Cr⁶⁺) to trivalent chromium (Cr³âº), making it safer for environmental discharge.

Manufacturing Process
Method 1: Reaction of Formic Acid with Sodium Hydroxide
Sodium formate is typically produced by neutralizing formic acid (HCOOH) with sodium hydroxide (NaOH) or sodium carbonate (Na₂CO₃):
HCOOH + NaOH → HCOONa + Hâ‚‚O
HCOOH + Naâ‚‚CO₃ → 2HCOONa + COâ‚‚ + Hâ‚‚O
This method results in high-purity sodium formate and is widely used in commercial production.
Method 2: By-Product of Pentaerythritol Production*
Sodium formate is also obtained as a by-product in the manufacturing of pentaerythritol, a key ingredient in alkyd resins and explosives. The process involves reacting formaldehyde with sodium hydroxid in the presence of excess methanol, yielding sodium formate as a secondary product.